Silver(I)-mediated highly enantioselective synthesis of axially chiral allenes under thermal and microwave-assisted conditions.
نویسندگان
چکیده
Silver(I) salts mediated stereospecific transformation of optically active propargylamines to axially chiral allenes with excellent enantioselectivities (17 examples with 96-99% ee; one substrate with 91% ee) without subsequent racemization.
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عنوان ژورنال:
- Chemical communications
دوره 46 2 شماره
صفحات -
تاریخ انتشار 2010